In the title compound, C11H11NO4S, the thiazine ring adopts a distorted half-chair conformation. The enolic H atom is involved in an intramolecular O—H⋯O hydrogen bond, forming a six-membered ring. Molecules are linked through weak intermolecular C—H⋯O hydrogen bonds, resulting in chains lying along the b axis.
The structures of N-benzyl-N'-{6-[(4-carboxylatobenzyl)aminocarbonyl]-2-pyridylmethyl}guanidinium, C(23)H(23)N(5)O(3), (I), and N-[2-(benzylaminocarbonyl)ethyl]-N'-{6-[(4-carboxylatobenzyl)aminocarbonyl]-2-pyridylmethyl}guanidinium monohydrate, C(26)H(28)N(6)O(4).H(2)O, (II), both form three-dimensional supramolecular hydrogen-bonded networks based on a dimeric primary synthon involving carboxylate-guanidinium linkages. The differences in the geometries and hydrogen-bonding connectivities are driven by the additional methylpropionamide group and water of crystallization of (II).
This paper presents real time performance analysis of a silica gel based desiccant wheel dehumidifier. Thermodynamic model is also validated through comparison under a wide range of operating conditions for subtropical climate conditions. Initially, a mathematical model is developed by using various set of equations for desiccant wheel dehumidifier in engineering equation solver. Afterwards, a parametric analysis of the system is performed including various design and climate parameters such as: inlet air humidity ratio, inlet air temperature, regeneration inlet humidity ratio, regeneration temperature, and rotation speed of the wheel. Then, an experimental setup of the system is established in Taxila Pakistan for the real-time performance assessment. The results revealed that the optimal rotation speed of desiccant wheel ranged from 15-17 rph. The maximum model based and experimental effectiveness is 0.45 and 0.43, respectively at regeneration temperature of 80 °C. The maximum and minimum root mean square error values for effectiveness are 3.2% and 2.1%, respectively. Thus, the comparison between experimental and model results showed a good agreement.
In the title compound, C13H13NO6S, the thiazine ring adopts a distorted half-chair conformation. Each molecule is linked to its neighbour through intermolecular C—H⋯O hydrogen bonds.
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