A simple method used to construct microparticles of porous Si photonic crystals that display highly resolved and easily controlled optical diffraction peaks is described. The spectral diffraction peaks can act as digits in an encoding scheme, and the possibility of generating particle libraries with >106 distinct codes is demonstrated (see Figure).
The flower of Pueraria thunbergiana BENTH (PTBF) contains isoflavonoids and essential oil components. It has many biological and pharmacological activities, including anti-diabetes, anti-oxidant, and weight loss. However, its effect on skin regeneration remains unknown. In the present study, we isolated the absolute from PTBF through solvent extraction and determined the role of the absolute on skin regeneration-associated responses in human epidermal-keratinocytes (HaCats). The PTBF absolute, which contained 10 compounds, stimulated migration and proliferation and increased the phosphorylation of serine/threonine-specific protein kinase and extracellular signal-regulated kinase1/2 in HaCats. It induced type I and IV collagen synthesis in HaCats. In addition, treatment with PTBF absolute resulted in increased sprout outgrowth in HaCats. These findings suggest that PTBF absolute may participate in skin regeneration, probably through promotion of migration, proliferation, and collagen synthesis.
Palladium pincer complexes composed of six-membered fused metallacycles have been synthesized directly
from 1,3-bis(2-pyridyloxy)benzene. The pincer complexes show
remarkably high turnover numbers and frequencies in the Heck
reaction.
Free-standing porous Si multilayer dielectric mirrors, prepared by electrochemical etching of crystalline Si, are treated with a ruthenium ring-opening metathesis polymerization (ROMP) catalyst followed by norbornene to produce flexible, stable composite materials in which poly(norbornene) is covalently attached to the porous Si matrix.
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