249ChemInform Abstract Addition of the aromatic hydroxy and amino nitriles (I) to 4-chlorobutyl isocyanate (II) and subsequent ring closure yield the fused diazepines (IV) which are also prepared by thermolysis of (III) or direct cyclization of (I) with (II).
Reaction of the 6‐substituted 2,3‐diphenylindole (I) with chlorosulfonyl isocyanate (II) or chlorocarbonyl isocyanate (IV) and subsequent aluminum or iron trichloride catalyzed cyclization yield the tricyclic heterocycles (III) and (V).
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