R 3 space), and (b) in terms of coordinates x, )S and z and the functions u(r), v(r) and w(r A three-dimensional X-ray diffraction study of sodium thiosulphate pentahydrate was based on densitometer-measured photographic data. The structure was refined by full-matrix least squares to an R (excluding zero-weight data) of 0.082 for 1301 reflexions and an R (including zero-weight data) of 0.089 for 1359 reflexions. The Na-O distances range from 2.386
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