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The methods of description of isotherms and thermodynamic characteristics of methane adsorp tion on active carbons PAU 10 and AUK in the broad temperature range below and above critical have been considered.

A method is proposed for a priori calculating adsorption isotherms based on the combination of the molecular dynamics method and Dubinin-Radushkevich and Tolmachev-Aranovich equations. The isotherms of adsorption of individual gases and vapors, as well as components of gaseous and vaporous mix tures and liquid solutions on microporous active carbons, are calculated using this method.

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