A method for the synthesis of O,O-diethyl (N-benzoyl)trichloroacetimidoylphosphonate (1) by successive reaction of N-(l-diethoxyphosphoryl-2,2-dichlorovinyl)benzamide with Me3SiCI and CI 2 was proposed. The reaction of phosphouate 1 with R3P follows the [4+1] cycloaddition mechanism to give phosphoranes, whose stability and further transformations are controlled by the nature of R.
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