These findings suggest that the umbilical cord blood CCL17 may be involved in the pathogenesis of infantile AD and in fetomaternal inheritance. Serum levels of CCL17 from umbilical cord blood may be a predictive marker for AD in infancy.
Fixed chirality: The treatment of cyclooctapyrroles (see picture) with a metal source with optically active carboxylate or amine ligands leads to enantioselective metalation to give stereochemically stable helical mononuclear and dinuclear complexes without a chiral auxiliary. The helicity of the dicopper complex was determined by the simulation of the CD spectrum on the basis of X‐ray crystallographic data.
The differences in the inflammatory cytokine value between CSF and serum suggest that the degree of systemic vasculitis is different between CSF and the circulating blood, and some patients with KD showed a higher degree of CSF inflammation.
gem-dimethylisocorrole gave four-coordinate Ni (II) and Cu (II) complexes, five-coordinate (chloro) Fe (III) and (chloro) Mn (III) complexes, and six-coordinate (chloro)(pyridinato) Rh (III) complex in moderate to good yields. The dinuclear complexes such as the μ-oxo-diiron(III) complex and tetracarbonyldirhodium(I) complex were also prepared. The structures of these mononuclear and dinuclear complexes were determined by X-ray crystallography. These structures are very similar to those of the corresponding metaloporphyrins but the presence of the sp3-meso carbon allows tilting of the pyrrole rings so as to adapt itself to various metal coordination geometries.
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