Enantioselective syntheses
Enantioselective syntheses O 0031Enantioselective Alkylation Using a New C 3 Symmetric Amine-Based Chiral Phase-Transfer Catalyst. -Novel C 3 -symmetric amine-based chiral triols (15 examples) are prepared and used as catalyst in the asymmetric alkylation of the glycinate-benzophenone Schiff base (II). Up to 58% e.e. are obtained. -(MASE, N.; OHNO, T.; HOSHIKAWA, N.; OHISHI, K.; MORIMOTO, H.; YODA, H.; TAKABE*, K.; Tetrahedron Lett. 44 (2003) 21, 4073-4075; Dep. Mol. Sci., Fac. Eng., Shizuoka Univ., Hamamatsu, Shizuoka 432, Japan; Eng.) -Mais 34-019
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