In this work a standoff Raman spectroscopy SRS system has been designed, assembled and tested for detecting explosives (Ammonium nitrate, Trinitrotoluene and Urea nitrate) in dark laboratory at 4 m target-telescope distance. The SRS system employs frequency doubled Nd:YAG laser at 532 nm excitation with laser power of 250 mW and integration time of 2 second. The Cassegrain telescope was coupled to the Ventana Raman spectrometer using a fiber optics cable, and Notch filter is used to reject Rayleigh scattering light. The Raman scattered light is collected by a telescope and then transferred via fiber optic to spectrometer and finally directed into charge coupled device CCD detector. In order to test SRS system, it has been used to detect the Raman spectra of Toxic Industrial Compounds TIC such as acetone, toluene, and carbon tetrachloride. The SRS results were compared with conventional Raman microscopy results using a bench top Bruker SENTERRA Raman instrument.
In this paper influence of laser energy on the emission spectrum of laser copper-interaction and plasma parameter for plasma Copper by used a first harmonic generated wavelength of Nd:YAG exaction source. The metal plasma that had detection by HR4000 detection system (ocean optics) was use to different excited. plasma temperature via the Boltzmann plot diagram with measuring the electron density number by McWhirter CRITERION. Values of measuring (Ne), (Te) found between (61178776 K°) and (Ne) is (1.77*1015, 2.01*1015 cm−3) at 1064nm.
The fluorescence spectroscopy (FS) is increasingly used in petroleum technology due the availability of better optical detection techniques, because FS offers high sensitivity, good diagnostic potential, and relatively simple instrumentation. Absorption and fluorescence spectrum of crude oil was studied at room temperature using optical path cuvette 1 cm. In this work, the absorption spectra were scanned (190-1100) nm while the emission spectra were obtained at different excitation wavelengths (266, 337, 420, and 488) nm. Crude oil was diluted by absolute ethanol to prepare different concentrations of crude oil. Ethanol as a solvent was used to dilute crude oil to obtain a solution transparent and the light could be transmitted. This work considers as an additional spectroscopic tool to develop into a fast responsive system for charchtrize the crude oil.
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