Densities and surface tensions were measured for the binary liquid mixtures formed by formamide, N-methylacetamide, di-methylformamide, and di-methylacetamide with acetonitrile at 293.15, 298.15, 303.15, and 313.15 K and atmospheric pressure over the whole concentration range. The Prigogine–Flory–Patterson model, the Ramaswamy and Anbananthan model, the model devised by Glinski, the Sanchez equation, the Goldsack relation, and the Eberhart model were used to predict the associational behaviour of weakly interacting liquids. The measured properties were fitted to the Redlich–Kister polynomial relation to estimate the binary coefficients and standard errors. Furthermore, the McAllister multibody interaction model was used to correlate the binary properties. These nonassociated and associated models were compared and tested for different systems showing that the associated processes yield fair agreement between theory and experiment compared with nonassociated processes.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.