We present the synthesis and detailed characterisation of the Rb x Mn[Fe(CN) 6 ] compound. The composition of the material significantly depends on the applied preparative conditions. Analysis of spectroscopic results (EDX, Raman) and X-ray powder diffraction data yielded a further assessment of the difference in structural features. The characteristic individual magnetic behaviour, as well as the metal-to-metal charge transfer capabilities of the various samples, could be related to significant changes within the structures that appear to be associated with the synthetic method used.

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