This paper describes a modelling study of dissolved heavy metals in riverine systems, undertaken to introduce a new approach of the varied reaction coefficients used in the Advection-Dispersion Equation (ADE). The dissolved heavy metals, i.e. lead and cadmium, were modelled using a 1D hydro-environmental model. It is found that pH and EC play an essential role in adsorption and desorption of heavy metals by the particles in solution. Therefore, in this study we have tried to find the best relationships between pH and EC with the reaction coefficient. Relatively close agreement between predicted results and field-measured dissolved lead and cadmium concentrations were obtained for different varied reaction coefficients. Finally, the best relationships for the reaction coefficients for dissolved lead and cadmium were introduced and the results were successfully compared with the corresponding measured values.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.