Wastewater treatment is crucial to ensure a sustainable supply of clean water, especially for human use. Natural flocculants can overcome the disadvantages of chemical flocculants in wastewater treatment. This study proposes a new natural-based flocculant from the Tacca leontopetaloides plant for leachate treatment. The plant tuber was processed through gelatinization to produce Tacca leontopetaloides biopolymer flocculant (TBPF). The characterization of TBPF for flocculant properties was investigated, and the performance of TBPF on leachate treatment using a standard jar test procedure was examined at different pH values of leachate and TBPF dosages. The characteristics of TBPF in terms of amylose/amylopectin fraction, viscosity, and zeta potential were 26:74, 0.037–0.04 Pa·s, and −13.14 mV, respectively. The presence of –COOH and –OH structure in TBPF indicates the flocculant properties. TBPF reduced the turbidity, total suspended solids (TSS), and color from 218 NTU, 214 mg/L, 14201 PtCo to 45.8–54.5 NTU, 19.3–19.9 mg/L, and 852–994 PtCo, respectively, using 240 mg/L of TBPF at pH 3. These results show a high potential of the new plant-based TBPF for leachate treatment and water industry applications.

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High removal of heavy metals using plant-based bioflocculant under low concentration is required due to its low cost, abundant source, and nontoxicity for improved wastewater management and utilization in the water industry. This paper presents a treatment of synthetic wastewater using plant-based Tacca leontopetaloides biopolymer flocculant (TBPF) without modification on its structural polymer chains. It produced a high removal of heavy metals (Zn, Pb, Ni, and Cd) at a low concentration of TBPF dosage. In our previous report, TBPF was characterized and successfully reduced the turbidity, total suspended solids, and color for leachate treatment; however, its effectiveness for heavy metal removal has not been reported. The removal of these heavy metals was performed using a standard jar test procedure at different pH values of synthetic wastewater and TBPF dosages. The effects of hydroxide ion, pH, initial TBPF concentration, initial metal ion concentration, and TBPF dosage were examined using one factorial at the time (OFAT). The results show that the highest removal for Zn, Pb, Ni, and Cd metal ions were 98.4–98.5%, 79–80%, 97–98%, and 92–93%, respectively, using 120 mg/L dosage from the initial concentration of 10% TBPF at pH 10. The final concentrations for Zn, Pb, Ni, and Cd metal ions were 0.043–0.044, 0.41–0.43, 0.037–0.054, and 0.11–0.13 mg/L, respectively, which are below the Standard B discharge limit set by the Department of Environment (DOE), Malaysia. The results show that TBPF has a high potential for the removal of heavy metals, particularly Zn, Pb, Ni, and Cd, in real wastewater treatment.

The effect of natural rubber and glycerol addition on the mechanical performance of Tacca leontopetaloides biopolymer was investigated in this paper. The samples were formulated by varying blend ratios of latex natural rubber to glycerol; 40/30 (GM1), 50/5.85 (GM2), 60/30 (GM3), 40/10 (GM4) and 50/20 (GM5). The samples (GMs) were compounded by using two roll mill machine followed by vulcanization process with the presence of stearic acid and sulphur that act as curing agent. The sheet formed was cut into desired sizes, based on the analysis conducted. The mechanical performance of GMs was investigated by conducting tensile test, morphological structural analysis and water absorption test. The mechanical properties of GM2 showed a high tensile strength with low Young’s modulus compared to other GMs, thus indicating that GM2 was the superior combination of natural rubber to glycerol blend ratio. This, therefore, may be applied for the development of biopolymer with the properties of thermoplastic elastomer.