Abstract.1 The kinetics of copper ions adsorption by natural zeolite has been investigated in the apparatus with mechanical stirrer. The presence of external diffusion and pore diffusion area was established. For the external diffusive area, the dependence of mass transfer coefficient on stirrer rotation speed was confirmed; the dependence was described using a criterial equation. For the pore diffusion area, the equation is adduced by means of which the effective coefficient of pore diffusion was calculated.

Statics and kinetics of ammonium nitrogen absorption on natural zeolite were investigated experimentally under periodic conditions. A mathematical kinetics model was developed and a counterion diffusion coefficient was defined. The influence of phosphate compounds and protein on equilibrium and a rate of ammonium ion sorption was investigated.Keywords: ammonium nitrogen, zeolite, equilibrium, mathematical model, sewage water. СТАТИКА ТА КІНЕТИКА СОРБЦІЇ НІТРОГЕНУ АМОНІЙНОГО НА ПРИРОДНОМУ ЦЕОЛІТІ У ПЕРІОДИЧНИХ УМОВАХАнотація. Експериментально досліджено статику та кінетику поглинання нітроген амонію на природному сорбенті у періодичних умовах. Розроблено математичну модель кінетики, визначено коефіцієнт дифузії протиіонів. Досліджено вплив фосфатних сполук і білка на рівновагу та швидкість сорбції амонійного-йону.Ключові слова: нітроген амонійний, цеоліт, рівновага, математична модель, стічні води.

There is studied the ecological status of surface waters in Busk district. The attention is focused on the largest river Western Bug and its tributaries which essentially influence on the ecological condition. The analysis of hydrological monitoring in the basin of the Western Bug is done. Analysis of water pollution in the river is performed with use of fixed position state hydrological monitoring system posts. There are studied the data concerning pollution indicators for 2015 year and 3 seasons of 2016. A comparison of contamination in two points outside the district is carried out. There are considered river Poltva before its waters reach the district and flow into Western Bug and the river Western Bug after it lefts the district. The exceeding of the threshold limit values for some indicators is revealed. In all cases there is a slight excess of the TLV over the content of iron and ammonium ions. In Poltva have been considerable (3–6 times) exceeding the TLV for COD and BOD5, ammonium salt 8.4 times, total iron – 4.3 times, nitrites – in 6.75 times, suspended solids – 3.3 times, phenol – at 2.45 times. Therefore, the section of the city Buzka to the city Kamenka–Bug, Radekhiv bridge river water is not suitable for any water use. The self–cleaning of the water is happening within the district is and the second point of monitoring shows these indicators are within limits. The largest source of organic pollutants and nutrients into Western Bug River is the river Poltva. Insufficiently treated sewage of Lviv increases the level of water contamination. In the district however there are also a source of pollution of surface water with ions of ammonium and iron. For their identification the further observation are required.

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The dynamics of the adsorption process in the fixed-bed column was experimentally studied on the example of the system natural zeolite - water solution of copper salt with low concentrations, which are characteristic for wastewater treatment processes from toxic contaminants. The initial curves of the adsorption process for the height of the sorbent layer of 5 and 7 cm were constructed. The equilibrium of such processes can be described by Henry's linear equation. The adsorption process in the layer consists of two stages, which are examined in the study. The first stage is the formation of concentration front and the second one – its moving. The sum of the time of the first and second stages is the total adsorption time, which is determined before breakthrough time. The first stage of adsorption is mathematically formulated by the differential equation of molecular diffusion with a boundary condition of the first type. The second stage is supplemented by the balance equation, which takes into account not only the change of concentration in time, but also in the vertical coordinate and determines the time of movement of concentration front to breakthrough time. A mathematical model of the adsorption process in a fixed-bed column has been developed. Experimental data and theoretical calculations were compared. The results of statistical calculation of research results showed a satisfactory convergence of experimental and theoretical data.