Abstract. The present-day situation is such that industrial production, municipal economy, traffic, etc consume a continuously increasing amount of energy. As a result, the range of propagation of electric stray currents, including their appropriate potentials and leakage currents that affect building structures and facilities is expanded and this is of importance. It requires stricter demands regarding protection of building structures and facilities exposed to electric currents and potentials. This study gives the research data on the influence of structure on electrophysical properties, in particular specific electric resistance of the silicate compositions obtained for electrocorrosion protection. The theoretical research done allowed us to plot the relationships to define the specific electric resistance and the specific conductivity of a composite material using the data on its composition and the specific electric resistance of the filler and matrix. The algorithm to define the specific electric resistance of the composite material was developed for research and/or technological purposes by using the data on specific electric resistance of the filler, matrix and composition.