Trisdimethylaminophosphin reagiert mit Trimethylsilylazid unter Stickstoffentwicklung und Bildung von N‐Trimethylsilyl‐iminophosphorsäurehexamethyltriamid, (Me2N)3PNSiMe3. Unter Eliminierung von Dimethylamino‐trimethylsilan bildet sich daneben das Diphosphazen (Me2N)3PNP(NMe2)2NSiMe3. Die Umsetzung von Trimethylphosphit mit Trimethylsilylazid liefert neben dem erwarteten N‐Trimethylsilyl‐iminophosphorsäuretrimethylester, (MeO)3PNSiMe3, den isomeren N‐Trimethylsilyl‐N‐methyl‐aminophosphorsäuredimethylester, (MeO)2P(O)N(Me)SiMe3.
NOR 88CThe react i o n s of 2,2,2,4,4,4h exaf I u or0 -1 ,3d i met h y I -1 ,3d i aza -2,4d i p h 0s p h (v) et i d i n e with NN'd i I it h i o -A"'dimethylethylenediamine, and of the 1.3-t-butyl analogue with t-butyl-lithium gave rise to zwitterionic species.
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