The decays of the high angular momentum, high spin 4F0 states of the electron configuration 3s3p3d in aluminium-like ions (with three electrons outside a closed shell) have been identified in delayed spectra of foil excited Ti, Fe and Ni ion beams. The line identifications were aided by HXR, MCHF, and MCDF calculations and are corroborated by lifetime measurements which demonstrate the differential longevity of the fine structure levels. A search for the related case of ls2p3d4Fo level decays in Li-like ions of Si, P and S failed.
Levels of Ca ions with one, two or four electrons in the n = 3 shell have been studied for their decay properties and lifetimes. For the 3p 2 P o 1/2,3/2 levels of Ca X and the 3s3p 1 P o 1 level of Ca IX, arbitrarily normalized decay curve (ANDC) and cascade model analyses yield results with precisions of 10% and less and with low systematic uncertainties. The measured lifetime of the Ca IX 3s3d 1 D 2 level confirms the need to include relativistic effects in the calculation. The lifetime results are compared to other, experimental and theoretical, data available for the isoelectronic sequences.
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