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Inclusion compounds do not belong to the group of simple compounds. They consist of molecules of the host and guest components. Some of them form supermolecules and exhibit supermolecular properties.Combinations of inclusion compounds as even more complicated systems need more methods to be used for their identification. Thermoanalytical study enables to study the sorption during their formation and the progressive liberation of their individual components and parts. Many layered silicates, phosphates and other similar synthetic and natural compounds enclosing or adsorbing eyclodextrins, pharmaceuticals, aromatics, various agroehemieals and inorganics are analysed from the view of their formation and properties.