The Ultrasonic velocity(U), density(?), and viscosity(?) have been measured for the ternary liquid mixtures of N,N-Dimethyl Formamide (NNDMF), 1 butanol and n hexane at various temperatures viz., 303 k,308 k and 313 k at constant frequency 2 MHz. for different concentrations ranges from 0.001M to 0.01M. The acoustical parameters such as adiabatic compressibility(?), Rao constant(R), absorption coefficient (?/f2), internal pressure(?i), cohesive energy(CE), free volume(Vf), free length(Lf) and acoustic impedence(z), were calculated from the experimental data. These parameters in accordance with their ultrasonic velocities corresponding to different concentrations were discussed.
The parameters like density(ρ), ultrasonic velocity (U), and viscosity (η) were experimentally measured. The excess parameters like adiabatic compressibility, acoustic impedance, free volume, free length, internal pressure and ultrasonic velocity in addition to K value were computed from the experimental data. The variation of these parameters at a constant temperature for the three ternary systems, namely OMP + 1-pentanol+n-hexane, N, N-DMF + 1-pentanol+n-hexane, and MMP + 1-pentanol+n-hexane, have been discussed in the light of molecular interaction. Further, certain theoretical studies are validated with respect to experimental velocities, and the Chi-square test for the goodness of fit is also applied to check the validity of such theoretical models.
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