Mixing an aqueous solution of K8[Nb6O19]⋅16H2O with a DMSO/H2O solution of Cu(ClO4)2 · 6 H2O and cyclen at room temperature afforded crystallization of blue crystals of [(Cu(cyclen))6Nb6O19]⋅[ClO4]4·≈4H2O after slow evaporation of the solvents. The crystal structure contains the Lindqvist anion [Nb6O19]8– which is covalently expanded by six symmetry-related [Cu(cyclen)]2+ complexes via Nb-μ 2-O-Cu bridges yielding the positively charged [(Cu(cyclen))6Nb6O19]4+ cluster shell. The ClO4 − anions and crystal water molecules reside in the empty spaces of the packed clusters. The compound shows two electronic d-d transitions at energetic positions explaining the blue color.