Graphene oxide quantum
dot (GOQD) and reduced GOOD (rGOQD) were
synthetized using a simple and straight methodology based on an oxidative
treatment and sonication. GOQD and rGOQD were used as supporting agents
for the in situ generation of gold nanoparticles, avoiding the use
of additional stabilizers. GOQD resulted as a better support than
rGOQD because of the presence of higher functional groups that can
interact with gold. Theoretical studies through density functional
theory revealed the important role of the epoxy groups of GOQD on
the stabilization of gold. GOQD and GOQD-Au were tested for the first
time as catalysts for the decomposition of solid composite propellants.
GOQD not only lowered the decomposition temperature of ammonium perchlorate
(AP) but also enhanced the exothermic heat of AP, in comparison to
graphene and GO. GOQD-Au increased the energy release; however, the
effect on the decrease of the decomposition temperature of AP was
not as significant as other previous reported catalysts.
The synergistic effect of a copper and reduced graphene oxide nanocomposite increased the energy release in the thermal decomposition of ammonium perchlorate.
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