We report a new advance in the study of muonium (Mu)
reactivity;
specifically, we report the rate constant for the Mu + H2(vibrational quantum number n = 1) reaction determined
by measurements at 300 K and by converged quantum mechanical calculations.
Comparisons are made with earlier results for D + H2 (n = 1) and with the corresponding thermal reaction rates.
The measurements are a sensitive probe of the high-curvature region
in the entrance valley of the potential energy surface (PES) and thus
provide a qualitatively different probe of the PES than that provided
by any previous experiment.
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