The molecule of the title compound, C16H16N2, is centrosymmetric and the dihedral angle between the benzene ring and the dimethylhydrazine mean plane is 16.11 (15)°.
Crystals of the title compound, C12H14N4S, were obtained from a condensation reaction of 4-amino-3-ethyl-1H-1,2,4-triazole-5(4H)-thione and 2-methylbenzaldehyde. In the molecular structure, there is a short N=C double bond [1.255 (2) Å], and the benzene and triazole rings are located on opposite sites of this double bond. The two rings are approximately parallel to each other, the dihedral angle being 1.75 (11)°. A partially overlapped arrangement is observed between the nearly parallel triazole and benzene rings of adjacent molecules; the perpendicular distance of the centroid of the triazole ring from the benzene ring is 3.482 Å, indicating the existence of π–π stacking in the crystal structure.
The molecule of the title Schiff base compound, C7H8N2OS2, prepared by the reaction of methyl dithiocarbazate and furfural in an ethanol solution under reflux, adopts an E configuration; the dithiocarbazate and furan units are located on opposite sides of the C=N double bond. The planar dithiocarbazate group is twisted slightly with respect to the furan ring, making a dihedral angle of 5.2 (1)°. Adjacent molecules are linked by N—H⋯S hydrogen bonding to form a supramolecular dimer across an inversion center.
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