107, Taiwan, Republic of China a-(u-Bromoani1ino)alkenenitriles are converted t o 2-( methylamino)benzonitrile and varied y-carbolines by catalysis with palladium; the reactions may involve intramolecular aryl additions to the cyano group and other processessuch as cyano group transposition, electrocyclisation, ethyl group transfer and oxidative aromatisation.
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