No abstract

Acylphosphines are an overlooked subclass of phosphine ligands with specific reactivity and ligating properties. This study describes the synthesis of the first ferrocene-based acylphosphine, FcC(O)PPh2 (1, Fc = ferrocenyl), the...

Triazolium salts obtained from phosphinoferrocene alkyne and azide were used to prepare Au–carbene complexes, and P,C-chelating Pd or P,C-bridged Au–Pd phosphinocarbene complexes.

No abstract

A general challenging issue in the synthesis of hemilabile ferrocene ligands is the access to highly functionalized ferrocene starting materials. These can bear donor/acceptor atoms, additional functional and structuring spectator substituents, but the preparation of such species poses general synthetic difficulties. We report herein alternative synthetic routes to hybrid ferrocene donors such as tert-butylated phosphanylcarboxylic acids and their corresponding aldehydes. These hybrid ambiphilic species that combine Brønsted-acidic and [a]