One
of the biggest global challenges for our societies is to provide
natural resources to the rapidly expanding population while maintaining
sustainable and ecologically friendly products. The increasing public
concern about toxic insecticides has resulted in the rapid development
of alternative techniques based on natural infochemicals (ICs). ICs
(e.g., pheromones, allelochemicals, volatile organic compounds)
are secondary metabolites produced by plants and animals and used
as information vectors governing their interactions. Such chemical
language is the primary focus of chemical ecology, where behavior-modifying
chemicals are used as tools for green pest management. The success
of ecological programs highly depends on several factors, including
the amount of ICs that enclose the crop, the range of their diffusion,
and the uniformity of their application, which makes precise detection
and quantification of ICs essential for efficient and profitable pest
control. However, the sensing of such molecules remains challenging,
and the number of devices able to detect ICs in air is so far limited.
In this review, we will present the advances in sensing of ICs including
biochemical sensors mimicking the olfactory system, chemical sensors,
and sensor arrays (e-noses). We will also present several mathematical
models used in integrated pest management to describe how ICs diffuse
in the ambient air and how the structure of the odor plume affects
the pest dynamics.
The precise positioning of plasmonic nanoscale objects and organic molecules can significantly boost our ability to fabricate hybrid nanoarchitectures with specific target functionalities. In this work, we used a DNA origami structure to precisely localize three different fluorescent dyes close to the tips of hollow gold nanotriangles. A spectral dependence of plasmon-enhanced fluorescence is evidenced through co-localized AFM and fluorescence measurements. The experimental results match well with explanatory FDTD simulations. Our findings open the way to the bottom-up fabrication of plasmonic routers operating through plasmon energy transfer. They will allow one to actively control the direction of light propagation.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.