The
change in the pinning force during the transition from dry
to oil-impregnated thin polymer films is studied for droplets of water
and hexadecane. A careful variation of the oil amount in the films
is performed by means of supercritical impregnation. The film thickness
dependence on the oil content is measured using ellipsometry and compared
to gel swelling theory estimates. Depending on the oil content, two
cases of pinning force behavior have been identified. For each case,
the factors that determine the pinning force are discussed. The pinning
force in the transition from dry to equilibrium swollen gel films
is well approximated by the Joanny and de Gennes hysteresis model
of dilute defects.
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