Methylammonium lead iodide (CHNHPbI) (MAPI)-embedded β-phase comprising porous poly(vinylidene fluoride) (PVDF) composite (MPC) films turns to an excellent material for energy harvester and photodetector (PD). MAPI enables to nucleate up to ∼91% of electroactive phase in PVDF to make it suitable for piezoelectric-based mechanical energy harvesters (PEHs), sensors, and actuators. The piezoelectric energy generation from PEH made with MPC film has been demonstrated under a simple human finger touch motion. In addition, the feasibility of photosensitive properties of MPC films are manifested under the illumination of nonmonochromatic light, which also promises the application as organic photodetectors. Furthermore, fast rising time and instant increase in the current under light illumination have been observed in an MPC-based photodetector (PD), which indicates of its potential utility in efficient photoactive device. Owing to the photoresponsive and electroactive nature of MPC films, a new class of stand-alone self-powered flexible photoactive piezoelectric energy harvester (PPEH) has been fabricated. The simultaneous mechanical energy-harvesting and visible light detection capability of the PPEH is promising in piezo-phototronics technology.

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This work introduces a piezoelectric–pyroelectric nanogenerator (P-PNG) based on methylammonium lead iodide (CH3NH3PbI3) incorporated electrospun poly­(vinylidene fluoride) (PVDF) nanofibers that are able to harvest mechanical and thermal energies. During the application of a periodic compressive contact force at a frequency of 4 Hz, an output voltage of ∼220 mV is generated. The P-PNG has a piezoelectric coefficient (d 33) of ∼19.7 pC/N coupled with a high durability (60 000 cycles) and quick response time (∼1 ms). The maximum generated output power density (∼0.8 mW/m2) is sufficient to charge up a variety of capacitors, with the potential to replace an external power supply to drive portable devices. In addition, upon exposure to cyclic heating and cooling at a temperature of 38 K, a pyroelectric output current of 18.2 pA and a voltage of 41.78 mV were achieved. The fast response time of 1.14 s, reset time of 1.25 s, and pyroelectric coefficient of ∼44 pC/m2 K demonstrate a self-powered temperature sensing capability of the P-PNG. These characteristics make the P-PNG suitable for flexible piezoelectric–pyroelectric energy harvesting for self-powered electronic devices.

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Propylammonium lead iodide (C3H7NH3PbI3), a promising hybrid perovskite, is successfully synthesized by a solgel technique. Structural, optical, and dielectric properties have been studied in detail. The dielectric constant, loss factor, electric modulus, and AC and DC conductivity of this hybrid perovskite exhibit strong temperature dependence over the frequency range of 10 Hz ≤ f ≤ 8 MHz. The Nyquist plot reveals the distinct contributions of grain and grain boundary to the total impedance. The dielectric constant is found to increase with temperature in the high frequency region. The modified Cole–Cole plot shows that the space charge and free charge conductivity increase with the elevation of temperature, whereas the relaxation time decreases with the rise in temperature. From the modified Kohlrausch–Williams–Watts equation, we perceived asymmetrical nature in electric modulus spectra at various temperatures, which corresponds to the non-Debye type nature of perovskite. It has also been found that, with the elevation of temperature, the imaginary part of electric modulus spectra shifts from the non-Debye type toward the Debye type nature, though failing to acquire exact Debye type response, and emerges as a semiconductor material. AC conductivity of PAPbI3 is illustrated on the basis of the correlated barrier hopping (CBH) mechanism. Activation energy estimated from both modulus spectra and DC conductivity matches well, affirming the similarity between relaxation behavior and conduction mechanism. Along with all these, PAPbI3 possesses a high dielectric constant associated with a small dielectric loss, making it a potential candidate for energy harvesting devices.