____________________________________________________________________________Resumo: A Catequina é um composto fenólico com grande potencial oxidante, encontrada em diversos tipos de alimentos, dentre alguns dos benefícios da catequina estão o fortalecimento capilar, melhoria do fluxo sanguíneo, redução dos níveis de colesterol. Neste artigo, utilizou-se da técnica de voltametria cíclica (VC) para otimizar o eletrodo de carbono impresso modificado com nanotubo de carbono funcionalizado para detectar e quantificar catequina por meio da técnica de voltametria de onda quadrada (VOQ). Para este eletrodo, os melhores resultados foram obtidos a uma concentração de 1x10 -3 mol L -1 de catequina em meio de tampão fosfato 0,1 mol L -1 pH 7,0 a uma velocidade de varredura de potencial de 0,05 V s -1 . A partir destas condições foi obtida uma curva analítica com comportamento linear no intervalo de concentração de catequina entre 2,0x10 -7 a 1,68x10, com limites de detecção e de quantificação de 9,2x10 -8 e 3,0x10 -7 mol L -1, respectivamente por VOQ. Este eletrodo apresentou boa repetibilidade com um desvio de padrão relativo de 4,05%. A oxidação da catequina apresentou um pico localizado em torno de 0,15V vs Ag/AgCl, estando próximo dos potenciais de pico mostrados na literatura.Palavras-chave: catequina, eletrodo de carbono impresso, nanotubo de carbono, sensor eletroquímico ____________________________________________________________________________ Abstract: Catechin is a phenolic compound with high oxidizing potential, found in several types of foods, some of the benefits of catechins are capillary strengthening, improvement of blood flow and reduction of cholesterol levels. In this paper, it was used the cyclic voltammetry technique (CV) to optimize the printed carbon electrode modified with carbon nanotube, functionalized to detect and quantify catechin by means of the squarewave voltammetry technique (SWV). For this electrode, the best results were obtained at a catechin concentration of 1x10 -3 mol L -1 in means of 0.1 mol L -1 phosphate buffer pH 7.0 at a potential scan rate of 0.05 V s -1 . From these conditions, an analytical curve was obtained with a linear behavior in the catechin concentration range of 1,68x10 -5 to 2,0x10 -7 mol L -1, with limits of detection and quantification of 9,2x10 -8 and 3,0x10 -7 mol L -1 , respectively, by SWV. This electrode showed good repeatability with a standard deviation of 4.05%. Oxidation of catechin showed a peak located around 0,15V vs Ag / AgCl, being close to the peak potentials shown in the literature.
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