The title compound, [Ag(C27H23BrN3O4)(CH3CN)2](PF6)2, is a mononuclear salt species in which the silver(I) atom is coordinated by one ligand and two acetonitrile mol­ecules and exhibits a distorted T-shaped coordination. The asymmetric unit contains one independent cation and two independent hexa­fluorido­phosphate anions, one of which is disordered over two positions in a 0.756 (11):0.244 (11) ratio. Weak π–π inter­actions between the anthraquinone ring systems [centroid–centroid distance = 3.676 (3) Å], inter­molecular Ag–π inter­actions [Cg⋯Ag = 3.405 Å] and C—H⋯π inter­actions between pairs of adjacent mol­ecules are observed.

The title compound, C25H24ClNO3, has three contiguous chiral centres. The absolute structure was determined by anomalous dispersion. The chloro­benzene ring is inclined to the two phenyl rings by 14.98 (9) and 59.05 (9)°. The two phenyl rings are inclined to one another by 49.51 (10)°. In the crystal, neighbouring mol­ecules are linked via C—H⋯O hydrogen bonds, forming chains propagating along [010]. There is also a C—H⋯π inter­action present that leads to the formation of a three-dimensional network.