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A c c e p t e d M a n u s c r i p t• Cathodic electrochemical deposition proposed to fabricate hematite nanoparticles.• Hematite nanoparticles were fabricated on indium-tin-oxide coated glass substrates.• The size and shape of nanoparticles were determined by deposition conditions.• The nanoparticles were well decentralized for different potential applications.• Electrochemical deposition is a useful approach in fabricating nanoparticles.

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