A D5h equatorial compressed ligand field of the central LnIII ion is achieved. The samarium complex is the first SmIII mono-nuclear complex with slow magnetic relaxation. The DyIII analogue, in contrast, relaxes much faster
Based on uncommon Kramers ions CeIII, SmIII and YbIII, complexes [Ce(dppbO2)2Cl3] (1, dppbO2 = 1,2-bis(diphenylphosphino)benzene dioxide), [Sm(dppbO2)2Cl3] (2) and [Yb(dppbO2)2Cl2]Cl (3) toward single-ion magnets were obtained and fully characterized. Complexes...
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