supposedly replaces the Zr 4þ sites. The traps and the glow curve structure are also dependent upon the morphology of the surface area which in turn depends on the nanocrystallite size. The nanocrystallite size depends also on the dopant ion. Furthermore, the obtained experimental results show that the presence of dopant ions also modifies the TL recombination efficiency which was found to be different for each irradiation type and the specific exposed material. It is important to notice that using the right dopant concentration, it is possible to maximize the TL efficiency and improve sensitivity and dose linearity for a specific irradiation type. For dual TL glow curve present in the sample it is very difficult to calculate the kinetic parameters from peak shape method. The kinetic parameters are calculated by (Computerized glow curve convolution technique) CGCD technique.
The present paper reports the thermoluminescence (TL) properties of combustion synthesized Ti doped ZrO 2 nanophosphors the effect of annealing on TL glow curve was also studied. The structural characterizations were done by X-ray diffraction technique (XRD), composition by Fourier transformation infrared spectroscopy and surface morphology was determined by field emission gun scanning electron microscopy (FEGSEM) technique. The prepared phosphor annealed at 600 C, 700 C, 800 C and 900 C and its thermoluminescence glow curve were recorded. The heating rate effect, the thermal quenching as well as the annealing temperature of the material were optimized for the TL glow curve of the sample. The TL glow curves for different UV, gamma doses and for Ti concentration were studied. The TL glow curve of prepared samples have glow peak at 173 C. The kinetic parameters was calculated by Computerized glow curve convolution technique (CGCD) technique. Fading and reusability studies of the nanophosphor further confirmed the phosphor's suitability for radiation dosimetry. The main conclusion is that Solution Combustion Synthesis is one of the appropriate method for synthesis of Ti doped ZrO 2 nanophosphors, which is suitable for temperature sensing applications, the post-synthesis annealing regime being one of the parameters that can affect the intensity and other parameters.
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