In the title compound, C25H23NO5S, the sulfonyl-bound benzene ring forms dihedral angles of 37.2 (1) and 67.0 (1)°, respectively, with the formylphenyl and phenyl rings. The molecular conformation is stabilized by an intramolecular C—H⋯π interaction. In the crystal, molecules are linked by C—H⋯O hydrogen bonds, forming a two-dimensional network in the (110) plane in which R
4
4(38) ring motifs are generated.
In the title compound, C19H17BrO4, the dihedral angle between the two benzene rings is 82.1 (1)°. The molecular structure is stabilized by an intramolecular C—H⋯O hydrogen bond which generates an S(7) ring motif. The crystal packing is stabilized by intermolecular C—H⋯O hydrogen bonds and C—H⋯π interactions. Intermolecular C—H⋯O interactions are involved in the formation of centrosymmetric R
2
2(16) dimers, which are connected into supramolecular tapes running along the [100] direction.
In the title compound, C11H10BrClO2, the dihedral angle between the benzene ring and the plane of the acrylate unit is 62.1 (1)°. The crystal packing is stabilzed by intermolecular C—H⋯O hydrogen bonds and C—Cl⋯π interactions [Cl⋯centroid = 3.829 (1) Å and C—Cl⋯centroid = 165.3 (1)°].
In the title compound, C24H19ClN2O3S, the sulfonyl-bound benzene ring forms dihedral angles of 38.1 (2) and 81.2 (1)°, respectively, with the formyl benzene and benzene rings. The molecular conformation is stabilized by a weak intramolecular C—H⋯O hydrogen bond, which generates an S(5) ring motif. The crystal packing is stabilized by C—H⋯O hydrogen bonds, which generate C(7) zigzag chains along [010] and R
3
3(19) ring motifs along [010]. The crystal packing is further stabilized by C—Cl⋯π interactions [Cl⋯centroid = 3.456 (2) Å and C—Cl⋯centroid = 173.4 (2)°].
In the title compound, C25H25NO5S, the O atom of the hydroxy group is disordered over two positions, with occupancies of 0.820 (2) and 0.180 (2). The sulfonyl-bound benzene ring forms dihedral angles of 31.8 (1) and 60.7 (1)°, respectively, with the hydroxymethylbenzene and phenyl rings. The molecular conformation is stabilized by an intramolecular O—H⋯O hydrogen bond, generating an S(8) ring motif. The crystal packing is stabilized by intermolecular C—H⋯O hydrogen bonds and C—H⋯π interactions.
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