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Zn2SnO4, an inverse spinel, and ZnFe2O4, a normal spinel, form a complete series of solid solutions in the system ZnO‐Fe2O33nO2. The variation of cell dimensions with composition varies from 0.8439 nm (ZnS2nO4) to 0.8660 nm (ZnS2nO4) and exhibits a positive deviation from a linear relationship. Mg2SnO4 and MgFe2O4, both predominantly inverse in nature, have only an incomplete series.

Die Phasenbeziehungen in den Titelsystemen werden unter besonderer Berücksichtigung der Sn‐ Spinellbildung untersucht.