The Structure of “;Trichloro‐diphenoxyphosphorane”
The structure of ‘Trichloro‐diphenoxyphosphorane’ synthesized by well‐known and new methods is not a pentacoordinated phosphorus compound, but has the structure of tetraphen‐oxyphosphonium hexachlorophosphate 4.
Aus Phosphorigsäureamiden und ‐chloriden wurden durch Reaktion mit N‐Chlordimethylamin bzw. Chlor die Dimethylaminophosphoniumsalze 3 und 4 dargestellt. Die Reaktion von Phosphortrichlorid mit N‐Chlordimethylamin bzw. von Dimethylamino‐dichlorphosphin mit Chlor führte zum Bis(dimethylamino)dichlorphosphonium‐hexachlorophosphat 7.
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