Various aspects related to the feasibility and design of continuous reactive distillation processes
are addressed in this paper. The recent developments in the field of reactive distillation design
are discussed. Then, a new type of reliable and systematic design method, which is based on
the “static analysis”, is explained. In this method, using minimal information about the
physicochemical properties of the reaction mixture, the possible degree of conversion and the
location of the reactive zone are calculated. The main feature of this method is that conventional
distillation lines can be used in the analysis by assuming an infinite separation efficiency. The
results of applying this method to the production of MTBE show that the feed region is classified
into several subregions, each of which has different characteristics.
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