A new film selenate selective electrode has been developed, with the following membrane composition: (3,4,5-tris-dodecyloxybenzyl)tetraoxyethyl trimethyl ammonium chloride (5% w/w) as an electroactive component, (poly)vinyl chlorid (33% w/w) as a membrane matrix, 1-bromonaphtalene (42% w/w) as a plasticizer, (4-trifluoroacetyl) benzoic acid heptyl ester (20% w/w) as a neutral anion carrier. The electrode characteristics are as follows: linear range -2•10 -6 -10 -2 М by Na 2 SeO 4 ; line plot slope 26,0±0,3 mV/decade; lower detection limit 1•10 -6 М by Na 2 SeO 4 ; working рН range 2,15 -6,3; potential drift 0,9 mV/h; response time 15 -90 s; selectivity in presence of chloride, bromide, sulfate and other ions; lifetime up to 3 weeks. The electrode developed has been tested on model solutions using the standard addition method in the calibration plot variant, and bracketing technique.