Selenidobis(dithiolene)molybdenum(IV) and -tungsten(IV) complexes were synthesized and characterized by several methods including X-ray crystallographic analysis. The five-coordinate M (V)Se species were accessed by one-electron oxidation of the M (IV)Se complexes. M (VI)Se complexes were suggested to be formed as an intermediate in oxygen atom transfer from Me 3NO to the M (IV)Se centers.
Sulfurization of five-coordinate [W(IV)O(1,2-benzenedithiolate)(2)](2-) proceeds under very mild conditions to form seven-coordinate [W(VI)O(eta(2)-S(2))(1,2-benzenedithiolate)(2)](2-), from which H(2)S was generated by treatment with H(2). This is the first functional model for the fourth tungsten-containing WOR4 enzyme. Kinetics and isotope-scrambling experiments have suggested the existence of six-coordinate W(V)(eta(1)-S(2)) species as a key reaction intermediate.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.