Richard T. Carl scite author profile

Photolysis of [Rh(q5-C5Me5)( I ,2,5,6-q-C8F8)] i n the presence of PMe3 leads to the crystallographically characterized title compound which contains a unique example of a 1,4-q-cyclo-octatetraene ligand; this compound is an intermediate en route t o formation of perfluorobicyclo[3.3.O]octadienediyl complexes.Cyclo-octatetraene (cot) has been a ligand of great significance in the development of organometallic chemistry. Its flexible hapticity has enabled compounds exhibiting a variety of co-ordination modes to be isolated.l.2 The transition metal chemistry of the corresponding fluorocarbon octafluorocyclooctatetraene (ofcot) (1) is significantly different3--5 and has

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Synthesis, structures, and solution dynamics of mononuclear and dinuclear (.eta.5-indenyl)rhodium complexes of octafluorocyclooctatetraene. Crystal and molecular structures of [Rh(.eta.5-C9H7)(1,2,5,6-.eta.-C8F8)], [[Rh(.eta.5-C9H7)]2[.mu.-(1,5,6-.eta.:2-4-.eta.-C8F8)](Rh-Rh)], [[Rh(.eta.5-C9H7)]2[.mu.-(1,5,6-.eta.:2-4-.eta.-C8F7H)](Rh-Rh)], and [[Rh(.eta.5-C9H7)(CO)][Rh(.eta.5-C9H7)][.mu.-(1,2,5,6-.eta.:7,8-.eta.-C8F8]]

Carl¹,

Hughes²,

Rheingold³

et al. 1988

Organometallics

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Unprecedented bonding of a coordinated polyenyl ligand. Synthesis and molecular structures of fac-trialkyltricarbonyliron compounds containing the .eta.3-nonafluorocycloocta-2,5-diene-1,4,7-triyl ligand and its derivatives

Carl¹,

Hughes²,

Johnson³

et al. 1987

J. Am. Chem. Soc.

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Transition-metal chemistry of octafluorocyclooctatetraene. Synthesis and x-ray structure of a novel five-coordinate cis-dialkylnickel complex

Hughes¹,

Carl²,

Samkoff³

et al. 1986

Organometallics

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Richard T. Carl

The CLAS Cherenkov detector

Unprecedented co-ordination of a cyclo-octatetraene ligand. Synthesis and crystal and molecular structure of (η-pentamethylcyclopentadienyl)(1,4-η-octafluorocyclooctatetraene)(trimethylphosphine)rhodium(III)

Unprecedented bonding of a coordinated polyenyl ligand. Synthesis and molecular structures of fac-trialkyltricarbonyliron compounds containing the .eta.3-nonafluorocycloocta-2,5-diene-1,4,7-triyl ligand and its derivatives

Transition-metal chemistry of octafluorocyclooctatetraene. Synthesis and x-ray structure of a novel five-coordinate cis-dialkylnickel complex

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