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Density F and viscosity η were measured for binary mixtures of cotton seed + babassu and soybean + babassu biodiesel over the composition range at several temperatures of (293.15, 313.15, 333.15, 353.15, and 373.15) K and atmospheric pressure. The viscosity deviation (∆η) was determined and fitted by a Redlich-Kister type function in terms of mass fraction (w). The Joback's method combined with Lee-Kesler and Rackett equations were used to calculate the densities of the binary mixtures of cotton seed + babassu and soybean + babassu biodiesel. The experimental and estimated density values gave almost identical values with a relative differences of less than 0.21 %. The Ceriani's group contribution method was used to predict the viscosity, with a maximum relative deviation of 31 %.

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a b s t r a c tIn this work, new UNIQUAC structural parameters r and q for the ionic liquids were determined by quantum chemistry calculations performed with the Gaussian 03 and GAMESS 7.1 packages, including the density functional theory (DFT) for the optimization of the structures and the polarizable continuum method (PCM) for the calculation of molecular areas and volumes. Data liquid-liquid equilibrium (LLE) of 41 ternary systems involving 15 different ionic liquids, comprising 379 experimental tie-lines, was correlated by the UNIQUAC model for the activity coefficient. The results, expressed by deviations between experimental and calculated compositions, are very satisfactory, with deviation values about 1.93%.