Studies on laboratory-scale submerged aerobic fixed film reactor (SAFF) packed with synthetic media having specific surface area of 165 m2/m3 with a void volume of 89% were carried out to assess its performance under various organic loading rates (OLR) and hydraulic retention times (HRT). Synthetic wastewater having chemical oxygen demand (COD) and biochemical oxygen demand (BOD) of 400 ± 10% and 210 ± 10% mg/L respectively was fed and the reactor was subjected to OLRs ranging from 0.37 to 1.26 kg COD/m3.d. It was observed that steady sloughing of biofilm occurs within the SAFF reactor all the times and average concentration of sloughed biomass in the effluent was 26 mg/L. The COD and BOD removal efficiencies varied between 85 and 89% and 86 to 94%, respectively. The kinetic studies demonstrated that SAFF reactor followed Stover–Kincannon and Grau models, with high correlation coefficients (R2) of 0.9977 and 0.9916, respectively. Thus, the values of kinetic coefficients such as maximum substrate utilization rate, Umax = 64.1 g/(L.d); saturation value constant, KB = 72.31 g/(L.d) and Grau second-order substrate removal rate constant, Ks = 2.44 day−1 can be useful to develop and design large scale SAFF reactors. Finally, the study reveals that the optimum range for OLR can vary within 0.68–0.94 kg COD/m3.d.
In this study, the addition of bentonite at different proportions as clay minerals and various thicknesses (4, 5, and 6 mm) of ceramic membranes were evaluated for proton and oxygen mass transfer coefficients. Bentonite (20% and 4 mm) was found optimum and was then employed to assess earthen microbial fuel cell (EMFC) performance for different substrates (kitchen waste (KW) slurry and leachate) under batch mode. Both substrates were added in different concentration of chemical oxygen demand (COD), i.e., 18, 15.2, 12.5, 9.7, and 6.9 g/L to EMFCs. The EMFC achieved superior organic removals for leachate (>96%). Intriguingly, the volatile fatty acids (VFAs) generation and consumption were different for each substrate. Each system expressed affinity towards acetic acid, but limited VFAs (acetic and propionic) were generated by KW while leachate generated acetic, propionic, and butyric. The leachate concentration having COD of 15.2 g/L produced the highest power density of 586.5 ± 38.8 mW/m3, while for KW, only 41.5 mW/m3 (6.9 g/L of COD for KW) was obtained. The study consolidates the need for an intermediate step to pre-treat the organic fraction of waste before its use for resource recovery. Bentonite was found as an effective clay mineral for manufacturing ceramic membranes.
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