Alkaline water electrolysis, a promising technology for
clean energy
storage, is constrained by extrinsic factors in addition to intrinsic
electrocatalytic activity. To begin to compare between catalytic materials
for electrolysis applications, these extrinsic factors must first
be understood and controlled. Here, we modify extrinsic electrode
properties and study the effects of bubble release to examine how
the electrode and surface design impact the performance of water electrolysis.
We fabricate robust and cost-effective electrodes through a sequential
three-dimensional (3D) printing and metal deposition procedure. Through
a systematic assessment of the deposition procedure, we confirm the
close relationship between extrinsic electrode properties (i.e., wettability, surface roughness, and electrochemically
active surface area) and electrochemical performance. Modifying the
electrode geometry, size, and electrolyte flow rate results in an
overpotential decrease and different bubble diameters and lifetimes
for the hydrogen (HER) and oxygen evolution reactions (OER). Hence,
we demonstrate the essential role of the electrode architecture and
forced electrolyte convection on bubble release. Additionally, we
confirm the suitability of ordered, Ni-coated 3D porous structures
by evaluating the HER/OER performance, bubble dissipation, and long-term
stability. Finally, we utilize the 3D porous electrode as a support
for studying a benchmark NiFe electrocatalyst, confirming the robustness
and effectiveness of 3D-printed electrodes for testing electrocatalytic
materials while extrinsic properties are precisely controlled. Overall,
we demonstrate that tailoring electrode architectures and surface
properties result in precise tuning of extrinsic electrode properties,
providing more reproducible and comparable conditions for testing
the efficiency of electrode materials for water electrolysis.
École nationale vétérinaire, 94i01 Maisons dlfovt RÉSUMÉ Quatre souches d'entérovirus du groupe I (Teschen-Talfan) ont été isolées à partir de petites enzooties de poliomyélite du Porc. La maladie et les lésions ont été reproduites chez le porcelet. La preuve est donc apportée de l'existence de la maladie de Talfan en France. SUMMARY ISOLATION OF THE TAI,FAN DISEASE VIRUS IN FRANCE Four strains of the enterovirus of group I (Teschen-Talfan) have been isolated from small enzooties of swine polyomyelitis. The disease and its lesions have been replicated in the piglet. Thus, the existence of Talfan's disease in France is proved.
Autrefois dépositaire du trésor des Kamehameha, aujourd'hui (( source permanente d'enseignement A Les cent ans du Musée Bishop, l à Hawaii Façade de l'édifice datant du XIX~ siècle où sont exposées la plupart des collections du Musée Bishop ; la Salle hawaiienne est à droite : et la Salle polynésienne est derrière la tour qui coiffe l'entrée du bâtiment.
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