Fused-ring pyrazoles offer a versatile platform for derivitization to give finely tuned and functional ligands in coordination assemblies. Here, we explore the pyrazolo[4,3-b]pyridine (HL1) and pyrazolo[3,4-c]pyridine (HL2) backbones and their...

The synthesis of two π-extended pyrazole ligands is reported, and their zinc(ii) and copper(ii) complexes are studied spectroscopically and crystallographically, revealing the influence of the fused naphthyl substituent.