Copper(I) fluoroalkoxide complexes bearing dinitrogen ligands were synthesized and the structure and reactivity of the complexes toward trifluoroethoxylation, pentafluoropropoxylation, and tetrafluoropropoxylation of aryl and heteroaryl bromides were investigated.
A selective cyclization of unsaturated barbiturates and amidines promoted by N-bromosuccinimide has been successfully developed to afford a vast variety of 5,4′-imidazolinyl spirobarbiturates in moderate to good yields. The present...
I2 and Mn(OAc)3 regulated annulation of 2-styrylanilines and β-keto esters is accomplished for chemoselective synthesis of 2-alkylquinolines and quinoline-2-carboxylates.
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