The effect of low frequency ultrasound (LFU) pretreatment prior to intermediate-wave infrared radiation (IW-IR) drying on water migration and quality attributes of carrot slices was investigated in this study. Results showed that the vacuole water of LFU pretreated carrot samples decreased, while the cytoplasm and intercellular space water increased by low-field nuclear magnetic resonance analysis. In addition, LFU pretreatment caused the disruption of cell structures and formation of micro-channels, resulting in significant (p<0.05) decrease of drying time required. The IW-IR dried carrot slices with LFU pretreatment showed higher β-carotene content and rehydration ratio in comparison with control samples. The color parameters of ultrasound pretreated dried carrot slices after dehydration were closer to the raw carrot samples. The results of electronic nose showed that the aromatic and volatile organic compounds of dried carrot increased by sonicated pretreatment, while the nitrogen oxides decreased, indicating that LFU can improve the flavor of dried carrot slices.
Cobalt phosphate materials were prepared in the present work in one step at room temperature using different raw materials and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and N 2 gas adsorption. Cobalt phosphates exhibit 3D flower-like structures, and the assembly of nanosheets (petals of the "flowers") of cobalt phosphate prepared with sodium phosphate and cobalt acetate as raw materials (denoted as Co-P(A)) is more incompact than that of cobalt phosphate prepared with diammonium hydrogen phosphate and cobalt nitrate as raw materials (denoted as Co-P(B)) due to the former's mildly basic environment. The cobalt phosphates show relatively high photocatalytic activity for H 2 evolution reaction (HER) in the presence of Eosin Y as a sensitizer in an aqueous triethanolamine solution. The activity of Co-P(A) (0.40 mmol h −1 g −1 ) exceeds that of Co-P(B) (0.19 mmol h −1 g −1 ), which can be attributed to a more dispersive nanosheet and larger BET-specific surface area of Co-P(A). The mechanisms of photocatalytic HER and the formation of flower-like Co 3 (PO 4 ) 2 were discussed. The present system comprising of only abundant elements contributes toward the development of cost-efficient solar HER to achieve sustainable development.
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