Like-charged solid interfaces repel and separate from one another as much as possible. Charged interfaces composed of self-assembled charged-molecules such as lipids or proteins are ubiquitous. The present study shows that although charged lipid-membranes are sufficiently rigid, in order to swell as much as possible, they deviate markedly from the behavior of typical like-charged solids when diluted below a critical concentration (ca. 15 wt %). Unexpectedly, they swell into lamellar structures with spacing that is up to four times shorter than the layers should assume (if filling the entire available space). This process is reversible with respect to changing the lipid concentration. Additionally, the research shows that, although the repulsion between charged interfaces increases with temperature, like-charged membranes, remarkably, condense with increasing temperature. This effect is also shown to be reversible. Our findings hold for a wide range of conditions including varying membrane charge density, bending rigidity, salt concentration, and conditions of typical living systems. We attribute the limited swelling and condensation of the net repulsive interfaces to their self-assembled character. Unlike solids, membranes can rearrange to gain an effective entropic attraction, which increases with temperature and compensates for the work required for condensing the bilayers. Our findings provide new insight into the thermodynamics and self-organization of like-charged interfaces composed of self-assembled molecules such as charged biomaterials and supramolecular assemblies that are widely found in synthetic and natural constructs.
The analysis of wave-packet dynamics may be greatly simplified when viewed in phase space. While harmonic oscillators are often used as a convenient platform to study wave packets, arbitrary state preparation in these systems is more challenging. Here, we demonstrate a direct measurement of the Wigner distribution of complex photon states in an anharmonic oscillator--a superconducting phase circuit, biased in the small anharmonicity regime. We apply our method on nondispersive wave packets to explicitly show phase locking in states prepared by a frequency chirp. This method requires a simple calibration, and is easily applicable in our system out to the fifth level.
Multi-level control of quantum coherence exponentially reduces communication and computation resources required for a variety of applications of quantum information science. However, it also introduces complex dynamics to be understood and controlled. These dynamics can be simplified and made intuitive by employing group theory to visualize certain four-level dynamics in a 'Bell frame' comprising an effective pair of uncoupled two-level qubits. We demonstrate control of a Josephson phase qudit with a single multi-tone excitation, achieving successive population inversions between the first and third levels and highlighting constraints imposed by the two-qubit representation. Furthermore, the finite anharmonicity of our system results in a rich dynamical evolution, where the two Bell-frame qubits undergo entangling-disentangling oscillations in time, explained by a Cartan gate decomposition representation. The Bell frame constitutes a promising tool for control of multi-level quantum systems, providing an intuitive clarity to complex dynamics.
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