A Cd(II)-based
metal–organic framework as fluorescent chemical
sensor, formulated as {[Cd3(bmipia)2]·10DMF·5H2O}
n
(FCS-2), was
synthesized through a hydrothermal process and structurally characterized
via X-ray crystallography. FCS-2 represented a new three-dimensional
framework assembled from a semi-rigid aromatic carboxylate ligand
and exhibited fascinating fluorescence due to the highly crystalline
and ordered molecular structure. The emission of FCS-2 could be quenched, interestingly, by the presence of trace 2,4,6-trinitrophenol,
which indicated that FCS-2 can be applied as a potentially
sensitive fluorescent chemical sensor for the detection of nitroaromatic
compounds.
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