Nitrogen-doped carbon quantum dots (NCQDs) were prepared from chitosan through a hydrothermal reaction. When ethanol precipitation was used as the purification method, a high product yield of 85.3% was obtained. A strong blue fluorescence emission with a high quantum yield (QY) of 6.6% was observed from the NCQD aqueous solution. Physical and chemical characteristics of the NCQDs were carefully investigated by transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectra (FTIR), Raman spectra, X-ray photoelectron spectroscopy (XPS), and transient fluorescence spectra. Experimental results showed that diameters of the NCQDs were in the range of 2–10 nm. The carbon quantum dots possess good water dispersibility and precipitation by ethanol. When used for metal ion detection, the detection limit of the NCQDs for Fe3+ was as low as 1.57 μM. This work proposed a facile method to synthesize NCQDs from chitosan with high yield and demonstrated that carbon quantum dots derived from chitosan were promising for ion detection.

Chitosan-based nanostructures have been widely applied in biomineralization and biosensors owing to its polycationic properties. The creation of chitosan nanostructures with controllable morphology is highly desirable, but has met with limited success yet. Here, we report that nanostructured chitosan tartaric sodium (CS-TA-Na) is simply synthesized in large amounts from chitosan tartaric ester (CS-TA) hydrolyzed by NaOH solution, while the CS-TA is obtained by dehydration-caused crystallization. The structures and self-assembly properties of CS-TA-Na are carefully characterized by Fourier-transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (1H-NMR), X-ray diffraction (XRD), differential scanning calorimeter (DSC), transmission electron microscopy (TEM), a scanning electron microscope (SEM) and a polarizing optical microscope (POM). As a result, the acquired nanostructured CS-TA-Na, which is dispersed in an aqueous solution 20–50 nm in length and 10–15 nm in width, shows both the features of carboxyl and amino functional groups. Moreover, morphology regulation of the CS-TA-Na nanostructures can be easily achieved by adjusting the solvent evaporation temperature. When the evaporation temperature is increased from 4 °C to 60 °C, CS-TA-Na nanorods and nanosheets are obtained on the substrates, respectively. As far as we know, this is the first report on using a simple solvent evaporation method to prepare CS-TA-Na nanocrystals with controllable morphologies.