, 4f-4f Transition spectral analysis to probe the kinetics for the complexation of Nd(III) with guanosine and guanosine triphosphate (GTP),

No abstract

In the title compound, C16H14N3OSCl, a Schiff base derivative of a thiosemicarbazide with a flavanone, the 4-chlorophenyl ring is inclined to the benzene ring of the chromane ring system by 30.72 (12)°. The pyran ring has an envelope conformation with the methine C atom as the flap. The mean plane of the thiourea unit is twisted with respect to the benzene ring of the chromanone ring system, subtending a dihedral angle of 19.78 (19)°. In the crystal, molecules are linked by two pairs of N—H...S hydrogen bonds, forming inversion dimers enclosing R 2 2(8) ring motifs, which are linked to form ribbons propagating along the b-axis direction. The intermolecular contacts in the crystal have been analysed using Hirshfeld surface analysis.